Dansk standard DS/ISO 15096 1. udgave 2008-08-25 Smykker Bestemmelse af sølv i 999- -sølv-legerede smykker Differensmetode ved brug af optisk ICP-emissionsspektrometri Jewellery Determination of silver in 999 silver jewellery alloys Difference method using inductively coupled plasma optical emission spectroscopy (ICP-OES)
DS/ISO 15096 København DS projekt: M219514 ICS: 39.060 Første del af denne publikations betegnelse er: DS/ISO, hvilket betyder, at det er en international standard, der har status som dansk standard Denne publikations overensstemmelse er: IDT med: ISO 15096:2008. DS-publikationen er på engelsk. DS-publikationstyper Dansk Standard udgiver forskellige publikationstyper. Typen på denne publikation fremgår af forsiden. Der kan være tale om: Dansk standard standard, der er udarbejdet på nationalt niveau, eller som er baseret på et andet lands nationale standard, eller standard, der er udarbejdet på internationalt og/eller europæisk niveau, og som har fået status som dansk standard DS-information publikation, der er udarbejdet på nationalt niveau, og som ikke har opnået status som standard, eller publikation, der er udarbejdet på internationalt og/eller europæisk niveau, og som ikke har fået status som standard, fx en teknisk rapport, eller europæisk præstandard DS-håndbog samling af standarder, eventuelt suppleret med informativt materiale DS-hæfte publikation med informativt materiale Til disse publikationstyper kan endvidere udgives tillæg og rettelsesblade DS-publikationsform Publikationstyperne udgives i forskellig form som henholdsvis fuldtekstpublikation (publikationen er trykt i sin helhed) godkendelsesblad (publikationen leveres i kopi med et trykt DS-omslag) elektronisk (publikationen leveres på et elektronisk medie) DS-betegnelse Alle DS-publikationers betegnelse begynder med DS efterfulgt af et eller flere præfikser og et nr., fx DS 383, DS/EN 5414 osv. Hvis der efter nr. er angivet et A eller Cor, betyder det, enten at det er et tillæg eller et rettelsesblad til hovedstandarden, eller at det er indført i hovedstandarden. DS-betegnelse angives på forsiden. Overensstemmelse med anden publikation: Overensstemmelse kan enten være IDT, EQV, NEQ eller MOD IDT: Når publikationen er identisk med en given publikation. EQV: Når publikationen teknisk er i overensstemmelse med en given publikation, men præsentationen er ændret. NEQ: Når publikationen teknisk eller præsentationsmæssigt ikke er i overensstemmelse med en given standard, men udarbejdet på baggrund af denne. MOD: Når publikationen er modificeret i forhold til en given publikation.
INTERNATIONAL STANDARD ISO 15096 First edition 2008-08-15 Jewellery Determination of silver in 999 silver jewellery alloys Difference method using inductively coupled plasma optical emission spectroscopy (ICP-OES) Joaillerie, bijouterie Dosage de l'argent dans les alliages d'argent 999 pour la joaillerie, bijouterie Méthode de la différence utilisant la spectrométrie d'émission à plasma induit par haute fréquence (ICP-OES) Reference number ISO 15096:2008(E) ISO 2008
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ISO 15096:2008(E) Foreword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 15096 was prepared by Technical Committee ISO/TC 174, Jewellery. ISO 2008 All rights reserved iii
INTERNATIONAL STANDARD ISO 15096:2008(E) Jewellery Determination of silver in 999 silver jewellery alloys Difference method using inductively coupled plasma optical emission spectroscopy (ICP-OES) 1 Scope This International Standard specifies the analytical procedure for the determination of silver in silver jewellery alloys, with a nominal content of 999 (parts per thousand), by measuring specific elements listed in Table A.1. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 11596, Jewellery Sampling of precious metal alloys for and in jewellery and associated products 3 Principle The samples of the silver alloys are weighed and dissolved in nitric acid to prepare a 10 g/l solution. Hydrochloric acid is added to precipitate the silver. The solutions are filtered to separate the silver chloride. The impurities are determined in the filtrate by inductively coupled plasma optical emission spectroscopy (ICP-OES), and the silver content is obtained by subtraction of the total content of impurities in the sample from 1 000. 4 Sampling The sampling procedure shall be performed in accordance with ISO 11596. NOTE Equivalent methods can be used, as described in ISO 5725-1. For coated articles, appropriate precautions that have been agreed upon shall be taken to exclude the coating from the determination. 5 Reagents During the analysis, unless otherwise stated, use only reagents of recognized analytical grade and only distilled water or water of equivalent purity. 5.1 Hydrochloric acid (HCl); ρ 20 = 1,16 g/cm 3 ; 32 % HCl (mass fraction). 5.2 Nitric acid (HNO 3 ); ρ 20 = 1,20 g/cm 3 ; 33 % HNO 3 (mass fraction). ISO 2008 All rights reserved 1